Near-IR photodissociation of peroxy acetyl nitrate
نویسندگان
چکیده
منابع مشابه
Near-IR photodissociation of peroxy acetyl nitrate
Measurements of the C-H overtone transition strengths combined with estimates of the photodissociation cross sections for these transitions suggest that near-IR photodissociation of peroxy acetyl nitrate (PAN) is less significant (Jnear−IR≈3×10 s−1 at noon) in the lower atmosphere than competing sinks resulting from unimolecular decomposition and ultraviolet photolysis. This is in contrast to t...
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Acyl peroxy nitrates (APNs, also known as PANs) are formed from the oxidation of aldehydes and other oxygenated VOC (oVOC) in the presence of NO2. There are both anthropogenic and biogenic oVOC precursors to APNs, but a detailed evaluation of this chemistry against observations has proven elusive. Here we describe measurements of PAN, PPN, and MPAN along with the majority of chemicals that part...
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Cavity ringdown spectra of butyl peroxy radicals have been obtained for their A-X electronic transition in the near-IR. The radicals were produced by two independent chemical methods, allowing unambiguous assignment of the spectra of the four butyl peroxy isomers with probable conformer assignments also possible for a number of cases. Using the analyzed spectra semiquantatively, isomer specific...
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Energy- and angle-resolved photofragment distributions for ground-state Cl ((2)P3/2) and spin-orbit excited Cl* ((2)P1/2) have been recorded using the velocity map imaging technique after photodissociation of chloroform at wavelengths of 193 and ∼235 nm. Translational energy distributions are rather broad and peak between 0.6 and 1.0 eV. The spin-orbit branching ratios [Cl*]/[Cl] are 1 and 0.3 ...
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ژورنال
عنوان ژورنال: Atmospheric Chemistry and Physics
سال: 2005
ISSN: 1680-7324
DOI: 10.5194/acp-5-385-2005